Preparation and Preliminary Dielectric Characterization of Structured C60-Thiol-Ene Polymer Nanocomposites Assembled Using the Thiol-Ene Click Reaction
نویسندگان
چکیده
منابع مشابه
Preparation and Preliminary Dielectric Characterization of Structured C60-Thiol-Ene Polymer Nanocomposites Assembled Using the Thiol-Ene Click Reaction
Fullerene-containing materials have the ability to store and release electrical energy. Therefore, fullerenes may ultimately find use in high-voltage equipment devices or as super capacitors for high electric energy storage due to this ease of manipulating their excellent dielectric properties and their high volume resistivity. A series of structured fullerene (C60) polymer nanocomposites were ...
متن کاملOn-resin peptide macrocyclization using thiol-ene click chemistry.
A versatile and rapid synthetic strategy has been developed for the on-resin cyclization of peptides using thiol-ene photochemistry. This unique method exploits the thiol group of natural cysteine amino acids and allows for various alkenes to be incorporated orthogonal to the peptide backbone.
متن کاملSynthesis of (Bio)degradable Polymers via Thiol-ene Click Polymerization
Towards the development of (bio)degradable polymers with medical relevance a non-radical thiolene synthesis route is investigated. In this work, step growth polymerization based on Michael addition click reactions is presented. Homotelechelic RAFT polymers were conjugated leading to polymers with molar weight distribution typical for a step growth polymerization, tailing up to 100 000 g∙mol-1 i...
متن کاملSynthetic applications of intramolecular thiol-ene "click" reactions.
The intermolecular thiol-ene reaction is emerging as a highly efficient; free-radical mediated "click" process with diverse applications in biofunctionalisation and materials science. The related intramolecular thiol-ene reactions offer significant potential for the preparation of a wide range of sulphur containing heterocycles including synthetic therapeutics such as cyclic peptides and thiosu...
متن کاملFunctionalization of Polymer Nanoparticles by Thiol-Ene Addition
Syndiotactic 1,2 polybutadiene nanoparticles (volume average diameter 13 nm) were func tionalized in aqueous dispersion by free radical mercaptan addition. By appropriate choice of both water soluble radical initiator andmercaptan concentration, nanoparticles with a degree of functionalization of up to 85% were prepared using 3 mercaptopropionic acid methyl ester and 3 mercaptopropionic acid. O...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Materials
سال: 2015
ISSN: 1996-1944
DOI: 10.3390/ma8115424